Formation Process of Zircon Associated with REE‐Fluorocarbonate and Niobium Minerals in the Nechalacho REE Deposit,Thor Lake,Canada     

Mihoko Hoshino  Yasushi Watanabe  Hiroyasu Murakami  Yoshiaki Kon  Maiko Tsunematsu 《Resource Geology》2013,63(1):1-26

The two drill holes, which penetrated sub‐horizontal rare earth element (REE) ore units at the Nechalacho REE in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify the enrichment mechanism of the high‐field‐strength elements (HFSE: Zr, Nb and REE). The REE ore units occur in the albitized and potassic altered miaskitic syenite. Zircon is the most common REE mineral in the REE ore units, and is divided into five types as follows: Type‐1 zircon occurs as discrete grains in phlogopite, and has a chemical character similar to igneous zircon. Type‐2 zircon consists of a porous HREE‐rich core and LREE–Nb–F‐rich rim. Enrichment of F in the rim of type‐2 zircon suggests that F was related to the enrichment of HFSE. The core of type‐2 zircon is regarded to be magmatic and the rim to be hydrothermal in origin. Type‐3 zircon is characterized by euhedral to anhedral crystals, which occur in a complex intergrowth with REE fluorocarbonates. Type‐3 zircon has high REE, Nb and F contents. Type‐4 zircon consists of porous‐core and ‐rim, but their chemical compositions are similar to each other. This zircon is a subhedral crystal rimmed by fergusonite. Type‐5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircon grains are filled by fergusonite. Type‐4 and type‐5 zircon grains have low REE, Nb and F contents. Type‐1 zircon is only included in one unit, which is less hydrothermally altered and mineralized. Type‐2 and type‐3 zircon grains mainly occur in the shallow units, while those of type‐4 and type‐5 are found in the deep units. The deep units have high HFSE contents and strongly altered mineral textures (type‐4 and type‐5) compared to the shallow units. Occurrences of these five types of zircon are different according to the depth and degree of the hydrothermal alteration by solutions rich in F and CO₃, which permit a model for the evolution of the zircon crystallization in the Nechalacho REE deposit as follows: (i) type‐1 (discrete magmatic zircon) is formed in miaskitic syenite. (ii) LREE–Nb–F‐rich hydrothermal zircon formed around HREE‐rich magmatic zircon (type‐2). (iii) type‐3 zircon crystallized through the F and CO₃‐rich hydrothermal alteration of type‐2 zircon which formed the complex intergrowth with REE fluorocarbonates; (iv) the CO₃‐rich hydrothermal fluid corroded type‐3, forming REE–Nb‐poor zircon (type‐4). Niobium and REE were no longer stable in the zircon structure and crystallized as fergusonite around the REE–Nb‐leached zircon (type‐4); (v) type‐5 zircon is formed by the more CO₃‐rich hydrothermal alteration of type‐4 zircon, suggested by the fact that type‐4 and type‐5 zircon grains are often included in ankerite. Type‐3 to type‐5 zircon grains at the Nechalacho REE deposit were continuously formed by leaching and/or dissolution of type‐2 zircon in the presence of F‐ and/or CO₃‐rich hydrothermal fluid. These mineral associations indicate that three representative hydrothermal stages were present and related to HFSE enrichment in the Nechalacho REE deposit: (i) F‐rich hydrothermal stage caused the crystallization of REE–Nb‐rich zircon (type‐2 rim and type‐3), with abundant formation of phlogopite and fluorite; (ii) F‐ and CO₃‐rich hydrothermal stage led to the replacement of a part of REE–Nb–F‐rich zircon by REE fluorocarbonate; and (iii) CO₃‐rich hydrothermal stage resulted in crystallization of the REE–Nb–F‐poor zircon and fergusonite, with ankerite. REE and Nb in hydrothermal fluid at the Nechalacho REE deposit were finally concentrated into fergusonite by way of REE–Nb–F‐rich zircon in the hydrothermally altered units.  相似文献   

Mercury concentration in some calcareous soils of western Iran with a focus on pedological evolution and weathering process     

Bubak Souri  Makiko Watanabe 《Environmental Earth Sciences》2013,70(3):1249-1262

The aim of this study was to evaluate total mercury concentration and its lithogenic and exogenic fractions in some calcareous soils of western Iran, where water contamination and bioaccumulation of mercury have been reported in the bottomland’s reservoir. In particular, we investigated soil physico-chemical properties and weathering conditions related to lithogenic and exogenic fractions of mercury for two groups of calcareous soils with a known comparative pedological evolution and weathering condition that was evident in the presence or absence of underlying layers of accumulated clay. Our results showed that the total mercury content of the studied soils ranged from 45.40 to 830.36 with a mean of 486.81 μg kg^?1. Furthermore, calculation of mercury fractions revealed that lithogenic and exogenic fractions vary slightly according to the three reference elements (Fe, U and Nb) used in the calculations for the two groups of studied soils. The results also illustrated that most of the mercury content is of exogenic origin; therefore, total mercury variations are closely related to the content of exogenic mercury, while the lithogenic fraction exhibited no relationship with total mercury concentration. Moreover, application of the weathering indexes of Parker and the CaO/ZrO₂ molar ratio supported the dependence of lithogenic mercury accumulation on weathering intensity in the studied calcareous soils. However, the significance of this relationship is stronger for more weathered calcareous soils; in such cases, fine-particle fractions are more developed, which encourages carrier phases such as organic materials and iron oxyhydroxides to become involved in more efficient fixation of mercury. Nevertheless, the formation of underlying layers of accumulated clay, i.e. argillic horizons, may restrain fixation of exogenic mercury by limiting its atmospheric input.  相似文献   

Geodynamics and Tectonics of Central Asia: Continental Growth in Vendian-Paleozoic Time     

M.M. Buslov  T. Watanabe  Y. Fujiwara  K. Iwata  Yu.I. Saphonova  O.T. Obut  Y. Sugai 《Gondwana Research》2001,4(4):587

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Petrological Indicators of Assembly and Breakup Processes for Precambrian Supercontinents at the Southern Margin of the Siberian Craton     

D.P. Gladkotchoub  T.V. Donskaya  E.V. Sklyarov  A.M. Mazukabzov  T. Watanabe 《Gondwana Research》2001,4(4):620

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Longitudinal patterns of genetic diversity and larval density of the riverine caddisfly Hydropsyche orientalis (Trichoptera)     

Kozo Watanabe  Michael T. Monaghan  Tatsuo Omura 《Aquatic Sciences - Research Across Boundaries》2008,70(4):377-387

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Preface     

Hiroyuki Tsubota  Masao Fukasawa  Koh Harada  Akira Nishimura  Masayuki Mac Takahashi  Shigeaki Aoki  Joji Ishizaka  Yutaka W. Watanabe 《Journal of Oceanography》1999,55(6):643-643

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Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E     

Yoshiyuki Takahashi  Eiji Matsumoto  Yutaka W. Watanabe 《Journal of Oceanography》1999,55(6):717-729

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.  相似文献   

Attenuation behaviour of tuffaceous sandstone and granite during microfracturing   总被引：1，自引：0，他引：1  

Angelika-M. Wulff  Toshiyuki Hashida  Kimio Watanabe  & Hideaki Takahashi 《Geophysical Journal International》1999,139(2):395-409

Laboratory measurements of ultrasonic wave propagation in tuffaceous sandstone (Kimachi, Japan) and granite (Iidate, Japan) were performed during increasing fracturing of the samples. The fracturing was achieved by unconfined uniaxial compression up to and beyond the point of macrofracture of the specimen using a constant low strain rate. The observed variation of wave velocity (up to 40 per cent) due to the development of micro- and macrofractures in the rock is interpreted by rock models relating velocity changes to damage and crack density. The calculated density of the newly formed cracks reaches higher values for the sandstone than for the granite. Using the estimated crack densities, the attenuation behaviour is interpreted in terms of different attenuation mechanisms; that is, friction and scattering. Rayleigh scattering as described by the model of Hudson (1981 ) may explain the attenuation qualitatively if the largest plausible crack dimensions are assumed in modelling.  相似文献   

Application of common reflection angle migration for imaging deformation structures in an inner accretionary wedge,Nankai Trough,Japan     

Kazuya Shiraishi  Masako Robb  Karl Hosgood  Yasuhiro Yamada 《Geophysical Prospecting》2019,67(2):317-330

To better image deformation structures within the inner accretionary wedge of the Nankai Trough, Japan, we apply common reflection angle migration to a legacy two-dimensional seismic data set acquired with a 6 km streamer cable. In this region, many seismic surveys have been conducted to study the seismogenic zone related to plate subduction. However, the details of the accreted sediments beneath the Kumano forearc basin are still unclear due to the poor quality of seismic images caused by multiple reflections, highly attenuated signals, and possibly complex geological structures. Generating common image gathers in the subsurface local angle domain rather than the surface offset domain is more advantageous for imaging geological structures that involve complex wave paths and poor illumination. By applying this method, previously unseen structures are revealed in the thick accreted sediments. The newly imaged geometric features of reflectors, such as the folds in the shallow part of the section and the deep reflectors with stepwise discontinuities, imply deformation structures with multiple thrust faults. The reflections within the deep accreted sediments (approximately 5 km) are mainly mapped to far angles (30°–50°) in the common reflection angles, which correspond to the recorded offset distances greater than 4.5 km. This result indicates that the far offset/angle information is critical to image the deformation structures at depth. The new depth image from the common reflection angle migration provides seismic evidence of multiple thrust faults and their relationship with the megathrust fault that is essential for understanding the structure and evolution of the Nankai Trough seismogenic zone.  相似文献   

The Wide Band Spectrometer on the SOLAR-A     

M. Yoshimori  K. Okudaira  Y. Hirasima  T. Igarashi  M. Akasaka  Y. Takai  K. Morimoto  T. Watanabe  K. Ohki  J. Nishimura  T. Yamagami  Y. Ogawara  I. Kondo 《Solar physics》1991,136(1):69-88

The SOLAR-A spacecraft has spectroscopic capabilities in a wide energy band from soft X-rays to gamma-rays. The Wide Band Spectrometer (WBS), consisting of three kinds of spectrometers, soft X-ray spectrometer (SXS), hard X-ray spectrometer (HXS) and gamma-ray spectrometer (GRS), is installed on SOLAR-A to investigate plasma heating, high-energy particle acceleration, and interaction processes. SXS has two proportional counters and each counter provides 128-channel pulse height data in the 2–30 keV range every 2 s and 2-channel pulse count data every 0.25 s. HXS has a NaI scintillation detector and provides 32-channel pulse height data in the 20–400 keV range every 1 s and 2-channel pulse count data every 0.125 s. GRS has two identical BGO scintillation detectors and each detector provides 128-channel pulse height data in the 0.2–10 MeV range every 4 s and 4-channel pulse count data (0.2–0.7, 0.7–4, 4–7, and 7–10 MeV) every 0.25–0.5 s. In addition, each of the BGO scintillation detectors provides 16-channel pulse height data in the 8–100 MeV range every 4 s and 2-channel pulse count data (8–30 and 30–100 MeV) every 0.5 s. The SXS observations enable one to study the thermal evolution of flare plasma by obtaining time series of electron temperatures and emission measures of hot plasma; the HXS observations enable one to study the electron acceleration and heating mechanisms by obtaining time series of the electron spectrum; and the GRS observations enable one to study the high-energy electron and ion acceleration and interaction processes by obtaining time series of electron and ion spectra.After the launch the name of SOLAR-A has been changed to YOHKOH.  相似文献